MENU

Physicochemical Characterization of Used Coconut Oil from Vacuum Frying of Jackfruit (Artocarpus heterophyllus Lam) Pulp EVIARC Sweet Variety as Affected by Frying Cycle

Jason D. Braga1, Roberta D. Lauzon2, and Lorina A. Galvez2*

1Institute of Food Science and Technology
College of Agriculture, Food, Environment, and Natural Resources
Cavite State University, Indang, Cavite, Philippines
2Department of Food Science and Technology
College of Agriculture and Food Science, Visayas State University
Baybay City, Leyte, Philippines


*Corresponding author: This email address is being protected from spambots. You need JavaScript enabled to view it.

 

 

ABSTRACT

This study was conducted to determine the quality of coconut oil (CO) used in a 2-h jackfruit pulp vacuum frying for 20 frying cycles. The % free fatty acid (FFA), acid value (AV), peroxide value (PV), moisture content (MC), and color of the CO used in vacuum frying was determined for unheated oil and oil after the 1st, 5th, 10th, 15th, and 20th cycle of frying. The FFA (0.273–0.554%), AV (0.543–1.102 NaOH/kg oil), PV (4.983–45.739 meq oxygen/kg), and MC (1.016–1.079%) showed significant increase (p <0.05) in the oil as the number of frying cycle increased that dictated the quality of the used CO. Hunter L and b showed significant (p < 0.05) effect on oil as the number of frying cycle increases, while Hunter a indicated insignificant effect. Based on the standard set by the Codex Alimentarius Commission (CAC) for refined CO (10 meq O2/kg oil), the oil quality is still safe after the third frying cycle, which conforms with the set standards for PV and AV. The pairing of these two tests is a good measure of oil quality assessment.

 


INTRODUCTION

Vegetable oil (crude, refined, bleached, and deodorized) is one of the main dietary components in the day to life food consumption and is used in nearly all types of food preparations – including frying, baking, sautéing, dressing, marinating, and extrusion cooking. They are generally obtained from oilseeds (i.e., mustard, sunflower, cottonseed, corn, and coconut); food legumes (i.e., soybean, peanut); nuts (i.e., almond); or the soft substances of fruits (i.e., olives). They are primarily composed of triacylglycerols, which consist of three fatty acids and one molecule of glycerol. The minor components of vegetable oil are FFAs, fat-soluble vitamins, pigments, phospholipids, waxes, sterols, and fatty alcohols (Foster et al. 2009). Vegetable oils contain different kinds of fatty acids and their compositions are widely varied; however, one type of fatty acid is generally predominant over the other fatty acids. The physical and chemical characteristics of vegetable oils are influenced by the quantity of fatty acid and the place, where it is positioned on the glycerol moiety (AOCS 2006). . . . read more

 


REFERENCES

ABDULKARIM SM, LONG K, LAI OM, MUHAMMAD SKS, GHAZALI HM. 2007. Frying quality and stability of high-oleic Moringa oleifera seed oil in comparison with other vegetable oils. Food Chem 105: 1382–1389.
AKINYEYEA RO, ADEYEYE EI, FASAKINA O, AGBOOLAA A. 2011. Physicochemical properties and anti-nutritional factors of palm fruit products (Elaeis guineensis Jacq.) from Ekiti State Nigeria. Electr J Environ Agri Food Chem 10: 2190–2198.
ANDRÉS-BELLO A, GARCÍA-SEGOVIA P, MARTÍNEZ-MONZÓ J. 2010. Vacuum frying process of gilthead sea bream (Sparus aurata) fillets. Inn Food Sci and Emer Techn 11: 630–633.
[AOAC] Association of Official Analytical Chemists. 1990. Official Methods of Analysis. In: Association of Official Analytical Chemists. Arlington, VA: AOAC Publishing. p. 69–84, 951–979.
[AOAC] Association of Official Analytical Chemists. 1995. Official Methods of Analysis, 15th edition. Arlington, VA: AOAC International.
[AOCS] American Oil Chemists’ Society. 1993. Official Methods and Recommended Practices of the American Oil Chemists’ Society. Washington, DC: AOCS Press.
[AOCS] American Oil Chemists' Society. 2006. Technical Committee of the Institute of Shortening and Edible Oils, Inc: Food fats and oils, 9th edition. Washington, DC.
BASUNY AM, ARAFAT SM, AHMED AA. 2012. Vacuum frying: An alternative to obtain high quality potato chips and fried oil. Glob Adv Res J Microbio 1(2): 19–26.
BREITENBACH J, SANDMANN G. 2005. ζ-Carotene cis isomers as products and substrates in the plant polycis carotenoid biosynthetic pathway to lycopene. Planta (220): 785–793.
CASTENMILLER J, WEST C. 1998. Bioavailability and bioconversion of carotenoids. Annu Rev Nutr (18): 19–38.
CHANDLER LA, SCHWARTZ SJ. 1988. Isomerization and losses of trans-beta-carotene in sweet potatoes as affected by processing treatments. J Agricultural and Food Chem, p. 129–133.
CHEN B, HUANG J. 1998. Degradation and isomerization of chlorophyll a and β-carotene as affected by various heating and illumination treatments. Food Chem 62: 299–307.
CHOE E, MIN DB. 2006. Mechanisms and factors for edible oil oxidation. Comp Rev Food Sci Food Safety (5): 169–186.
CHUNG J, LEE J, CHOE E. 2004. Oxidative stability of soybean and sesame oil mixture during frying of flour dough. J Food Sci (69): 574–578.
[CAC] Codex Alimentarius Commission. 2006. Codex Standards for Fats and Oils from Vegetable Sources. Rome: FAO.
DA SILVA P, MOREIRA R. 2008. Vacuum frying of high-quality fruit and vegetable based snacks. LWT Food Sci Tech (41): 1758–1767.
DAYRIT CS. 2003. Coconut Oil: Atherogenic or Not? (What Therefore Causes Atherosclerosis?). Phil J Cardiology (31): 97–104.
DAYRIT FM. 2014. Lauric acid is a medium-chain fatty acid, coconut oil is a medium-chain triglyceride. Philipp J Sci 143(2): 157–166.
DE FARIA AF, DE ROSSO VV, MERCADANTE AZ. 2009. Carotenoid composition of jackfruit (Artocarpus heterophyllus) determined by HPLC‐PDA‐MS/MS. J Plant Foods Hum Nutr (64): 108–115.
DUEIK V, BOUCHON P. 2011. Development of healthy low-fat snacks: Understanding the mechanisms of quality changes during atmospheric vacuum frying. Food Rev Intl 27: 408–432.
EYRES L, EYRES MF, CHISHOLM A, BROWN RC. 2016. Coconut oil consumption and cardiovascular risk factors in humans. Nutri Rev 74: 267–280.
FALADE A, OBOH G. 2015. Thermal oxidation induces lipid peroxidation and changes in  the  physico-chemical properties and β-carotene content of arachis oil. Int J Food Sci Vol. 2015, Article ID 806524, 7 pages. dx.doi.org/10.1155/2015/806524.
FOSTER R, WILLIAMSON CS, LUNN J. 2009. Briefing Paper: Culinary oils and their health effects. Nutr Bull 34: 4–47.
GOTOH N,  IWASAWA A, WATANABE H, OSATO R, WADA S. 2007. Oxidation of fats and oils in instant noodles stored under various conditions. J Food Lipids (14): 350–365.
GRANDA C, MOREIRA R, TICHY S. 2004. Reduction of acrylamide formation in potato chips by lowtemperature vacuum frying. J Food Sci (69): E405–E411.
GUO WH, TU CY, HU CH. 2008. Cis-trans isomerizations of β-carotene and lycopene: A theoretical study. J Phys Chem (112): 12158–12167.
HAQ N. 2006. Jackfruit (Artocarpus heterophyllus). Southampton, UK: International Centre for Underutilised Crops, University of Southampton.
HOLDEN JM, ELDRIDGE AL, BEECHER GR, BUZZARD IM, BHAGWAT S, DAVIS CS, DOUGLASS LW, GEBHARDT S, HAYTOWITZ D, SCHAKEL S. 1999. Carotenoid content of U.S. foods: An update of the database. J Food Compos Anal (12): 169–196.
KUKI M, KOYAMA Y, NAGAE H. 1991. Triplet-sensitized and thermal isomerization of all-trans, 7-cis,9-cis, 13-cis and 15-cis isomers of β-carotene: Configurational dependence of the quantum yield of isomerization via the T1 state. J Phys Chem (95): 7171–7180.
LOZANO-ALEJO N, CARRILLO G, PIXLEY K, PALACIOS-ROJAS N. 2007. Physical properties and carotenoid content of maize kernels and its nixtamalized snacks. Innov. Food Sci Emerg Technol (8): 385–389.
MANSOR TST, CHE MAN YB, SHUHAIMI M, ABDUL AFIQ MJ, KU NURUL FKM. 2012. Physicochemical properties of virgin coconut oil extracted from different processing methods. Int Food Res J 19(3): 837–845.
MARX M, STUPARIC M, SCHIEBER A, CARLE R. 2003. Effects of thermal processing on trans–cis isomerization of β-carotene in carrot juices and carotene-containing preparations. Food Chem (83): 609–617.
MATTHÄUS B. 2007. Use of palm oil for frying in comparison with other high-stability oils. Eur J Lipid Sci Tech 109(4): 400–409.
MÜLLER K, HARDWICK SJ, MARCHANT CE, LAW NS, WAEG G, ESTERBAUER H, CARPENTER KLH, MITCHINSON MJ. 1996. Cytotoxic and chemotactic potencies of several aldehydic components of oxidised low density lipoprotein for human monocyte-macrophages. FEBS Lett (388): 165–168.
NAZ S, SIDDIQI R, SHEIKH H, SAYEED S. 2005. Deterioration of olive, corn and soybean oils due to air, light, heat and deep-frying. Food Res. Int. (38): 127–134.
NIEDZWIEDZKI DM, SANDBERG DJ, CONG H, SANDBERG MN, GIBSON GN, BIRGE RR, FRANK HA. 2009. Ultrafast time resolved absorption spectroscopy of geometric isomers of carotenoids. Chem Phys (357): 4–16.
O’BRIEN RD. 1998. Fats and Oils, Formulating and Processing for Applications. Lancaster, PA: Technical Publishing Company, Inc.
OBOH G, FALADE AO, ADEMILUYI AO. 2014. Effect of thermal oxidation on the physico-chemical properties, malondialdehyde and carotenoid contents of palm oil. Riv Ital Sostanze Gr 91(1): 59–65.
PANGLOLI P, MELTON SL, COLLINS JL, PENFIELD MP, SAXTON AM. 2002. Flavour and storage stability of potato chips fried in cotton seed and sunflower oils and palm olein/sunflower oil blends. J Food Sci 67(1): 97–103.
PEDRESCHI F, MOYANO P, KAACK K, GRANBY K. 2005. Colour changes and acrylamide formation in fried potato slices. Food Res Int (38): 1–9.
PEDRESCHI F, MOYANO P, SANTIS N, PEDRESCHI R. 2007. Physical properties of pre-treated potato chips. J Food Eng (79): 1474–1482.
POSADA LR, SHI J, KAKUDA Y, XUE SJ. 2007. Extraction of tocotrienols from palm fatty acid distillates using molecular distillation. Separation and Purification Technology 57(2): 220–229.
QIU D, CHEN ZR, LI HR. 2009. Effect of heating on solid β-carotene. Food Chem (112): 344–349.
ROSA P, ALICIA S, ANGEL M. 1994. Determination of Free Fatty Acid in Foods by Flow Injection. J Sci Food and Agriculture (66): 473–479.
SCHIEBER A, CARLE R. 2005. Occurrence of carotenoid cis-isomers in food: Technological, analytical, and nutritional implications. Trends Food Sci Technol 16: 416–422.
SHIOZAWA S, TANAKA M, OHNO K, NAGAO Y, YAMADA T. 2007. Re-evaluation of Peroxide Value as an Indicator of the Quality of Edible Oils. J Food Hyg Soc Japan 48(3): 51–57.
SHYU S, HAU L, HWANG L. 1998. Effect of vacuum frying on the oxidative stability of oils. Journal of the American Oil Chemists’ Society 75: 1393–1398.
SHYU S, HWANG L. 2001. Effects of processing conditions on the quality of vacuum fried apple chips. Food Res Int (34): 133−142.
TABEE E, JÄGERSTAD M, DUTTA PC. 2009. Frying quality characteristics of French fries prepared in refined olive oil and palm olein. J Am Oil Chem Soc (86): 885–893.
TANG Y, CHEN B. 2000. Pigment change of freeze-dried carotenoid powder during storage. Food Chem 69: 11–17.
VASKOVA H, BUCKOVA M. 2015. Thermal degradation of vegetable oils: Spectroscopic measurement and analysis. Procedia Eng 100: 630–635.
VÁSQUEZ-CAICEDO A, SCHILLING S, CARLE R, NEIDHART S. 2007. Effects of thermal processing and fruit matrix on beta-carotene stability and enzyme inactivation during transformation of mangoes into purée and nectar. Food Chem (102): 1172–1186.
VELASCO J, MARMESAT S, DOBARGANES MC. 2008. Deep fat frying of foods. In: Chemistry of Frying. Sahin S, Sumnu G eds. p. 33–56. Philadelphia: Taylor and Francis.
YADAV S. 2018. Edible oil adulterations: Current issues, detection techniques, and health hazards. Intl J Chemical Studies 6(2): 1393–1397.